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What is Manganese Dioxide MnO2 Powder?

Risk aversion plunged on the positive news of the Russia-Ukraine talks. After several days of rising oil prices, the price of precious metals continued to fall. Domestic futures markets remain stable for the time being.

Back in international markets, WTI crude futures briefly dipped below $100 a barrel, while Brent crude hit its lowest intraday level in nearly two weeks. Spot gold briefly fell below $1,900 an ounce. Comex gold futures closed down 1.1 percent at $1,918.4 an ounce. Comex silver futures closed down 1.14 percent at $24.91 an ounce. "Recently, crude oil prices have been extremely sensitive to changes in geopolitical news." Traders believe that the current oil price is still in the broad impact, Ukraine will still be a premium in the case, although the market further decline, but should not be too pessimistic, it is recommended to wait and see for the time being. The Ukrainian premium is still there and there will be some volatility in the MnO2 market.

Introduction to Manganese Dioxide MnO2 Powder
Manganese dioxide is also known as manganese peroxide or black manganese oxide. It is the oxide of tetravalent manganese. The chemical formula is MnO2. The fHm (298K) is -520.71kJ/mol, the melting point is 847, and the density is 5.026 g/cm3. The natural MnO2 exists in pyrolusite, and it is a black rhombic crystal or black-brown powder. It has a tetrahedral lattice, which is amphoteric manganese oxide. It is insoluble in water and nitric acid, but gives off oxygen and forms manganese sulfate in hot concentrated sulfuric acid and is chlorinated to manganese chloride in hydrochloric acid. It is fused with caustic soda and oxidant, giving off carbon dioxide to form permanganate. Manganese dioxide is a strong oxidant and can cause combustion and explosion by friction or co-heating with organic matter or other oxidable substances such as sulfur, sulfide, and phosphide. The product exhibits reducibility with strong oxidants such as hydrogen peroxide. MnO2 is converted into Mn2O3 when heated above 480 in air, and Mn3O4 when heated above 900. It is widely used in steelmaking, glass, ceramics, dry cells, etc.
 
In nature, it exists in the form of pyrolusite and hard manganese ore. It can be extracted from pyrolusite, and can also be prepared by heating decomposition of manganese nitrate or electrolytic manganese dioxide salt. γ -Mno2 is active and can be used as a cathode material for batteries to eliminate polarization. Manganese dioxide can be used as a rust remover, oxidizer, dry battery drying agent, and paint drying agent, also used in manganese salt preparation and the glass industry. 
 

Physicochemical Properties of Manganese Dioxide MnO2 Powder
For manganese dioxide, oxygen atoms are at the top of the octahedron corner and manganese atoms in the octahedron. Octahedron is connected to form a single chain or double chain, forming a tunnel structure of the gap, octahedron, or hexagonal dense or square dense accumulation. Oxidizability: Manganese dioxide is a non-salt oxide, non-amphoteric oxide which does not react with either acid or base. In the presence of reducing agents, is oxidizing. Such as manganese dioxide into the hydrogen flow heating to 1400K to get manganese oxide. Manganese dioxide is heated in an ammonia gas stream to obtain brown and black manganese trioxide. Manganese dioxide is reacted with concentrated hydrochloric acid to obtain manganese chloride, chlorine gas, and water.
 
In the presence of strong oxidants, it also exhibits reducibility. If the manganese dioxide, potassium carbonate, and potassium nitrate or potassium chlorate mixed melting, people can get dark green melt, melt it in water cooling people can get six valence manganese compound potassium manganate. It is a strong oxidant in an acid medium. Strong oxidant, does not burn on its own, but it aids combustion, so please do not place it with flammable materials.
 

Manganese Dioxide MnO2 Powder Properties
Other Names manganese oxide, MnO2 powder
CAS No. 1313-13-9
Compound Formula MnO2
Molecular Weight 86.94
Appearance black powder
Melting Point 535°C
Boiling Point N/A
Density 5.03g/cm3
Solubility in H2O insoluble
Exact Mass 86.9279

 

Manganese Dioxide MnO2 CAS 1313-13-9
 

 
Applications of Manganese Dioxide MnO2 Powder
1. Manganese dioxide is a very good decolorizing agent in the glass manufacturing industry, which can oxidize low ferric salt to high ferric salt, so that the blue-green glass into weak yellow.
2. In the electronic industry it is used to produce manganese zinc ferrite magnetic materials.  
3. Used as the raw material of iron and manganese alloy in the steelmaking industry and heating agent in the casting industry. 
4. Used in gas masks to absorb carbon monoxide. 
5. In the chemical industry it can be used as an oxidant, catalyst for organic synthesis, paint, and ink desiccant.
6. Used as an accelerant for match industry, as a raw material for glaze medicine of ceramics and enamel and manganese salt. 
7. Used for fireworks, water purification, iron removal, medicine, fertilizer and textile printing, dyeing, etc.  
8. Electrolytic manganese dioxide is an excellent depolarizing agent of battery. Compared with the dry battery produced by natural discharge manganese dioxide, it has the characteristics of large discharge capacity, strong activity, small volume, and long life, so electrolytic manganese dioxide has become a very important raw material in the battery industry. 
9. Electrolytic manganese dioxide due to its strong catalytic, oxidation/reduction, ion exchange, and adsorption capacity, after treatment and molding, it is a comprehensive excellent water purification filter material. Compared with the common use of activated carbon, zeolite, and other water purification filter material, it has a stronger ability to decolorize and remove metal. 
 

Main Supplier of Manganese Dioxide MnO2 Powder
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and Nanomaterials, including silicon powder, nitride powder, graphite powder, zinc sulfide, calcium nitride, 3D printing powder, etc.
If you are looking for high-quality manganese dioxide MnO2 powder, please feel free to contact us and send an inquiry. ([email protected])

 

Europe has been facing the gas shortage problem since the second half of 2021. The worsening situation in Russia and Ukraine has reduced Russian gas shipments to Europe, leading to a doubling of European gas prices. Energy shortages have sent electricity prices soaring. For these reasons, it is predicted that the price of the MnO2 will continue to increase.

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